There is no evidence for the formation of the hydroxide, Pb(OH) 2, in aqueous solution below pH 12. The cation 4+ is unusual in having an oxide ion inside a cluster of 3 face-sharing PbO 4 tetrahedra. Pb 2(OH) 2(NO 3) 2 is the predominant species formed at low pH. It is soluble in water and dilute nitric acid.īasic nitrates are formed in when alkali is added to a solution. ![]() Lead nitrate decomposes on heating, a property that has been used in pyrotechnics. Solubility of lead nitrate in nitric acid at 26 ☌. Research interest in the crystal structure of lead(II) nitrate was partly based on the possibility of free internal rotation of the nitrate groups within the crystal lattice at elevated temperatures, but this did not materialise. All N–O bond lengths are identical, at 127 picometres. In this configuration, every lead atom is bonded to twelve oxygen atoms ( bond length: 281 pm). The black dots represent the lead atoms, the white dots the nitrate groups 27 picometres above the plane of the lead atoms, and the blue dots the nitrate groups the same distance below this plane. ![]() Its space group is Pa3 Z=4 ( Bravais lattice notation), with each side of the cube with length 784 picometres. The compound crystallizes in the cubic system with the lead atoms in a face-centred cubic system. The crystal structure of solid lead(II) nitrate has been determined by neutron diffraction. Structure Coordination sphere of the Pb 2+ ion Crystal structure of Pb(NO 3) 2 plane Solutions and crystals of lead(II) nitrate are formed in the processing of lead– bismuth wastes from lead refineries. It may also be obtained evaporation of the solution obtained by reacting metallic lead with dilute nitric acid. Lead nitrate is produced by reaction of lead(II) oxide with concentrated nitric acid: PbO + 2 HNO 3(concentrated) → Pb(NO 3) 2↓ + H 2O It has been used as an oxidizer in black powder and together with lead azide in special explosives. These pigments were used for dyeing and printing calico and other textiles. It has been produced as a raw material for making pigments such as chrome yellow (lead(II) chromate, PbCrO 4) and chrome orange (basic lead(II) chromate, Pb 2CrO 5) and Naples yellow. It is produced commercially by reaction of metallic lead with concentrated nitric acid in which it is sparingly soluble. Lead nitrate was first identified in 1597 by the alchemist Andreas Libavius, who called the substance plumbum dulce, meaning "sweet lead", because of its taste. Due to its hazardous nature, the limited applications of lead(II) nitrate are under constant scrutiny. Lead(II) nitrate is toxic and must be handled with care to prevent inhalation, ingestion and skin contact. ![]() Since around the year 2000, lead(II) nitrate has begun to be used in gold cyanidation. Other industrial uses included heat stabilization in nylon and polyesters, and in coatings of photothermographic paper. Historically, the main use was as a raw material in the production of pigments for lead paints, but such paints have been superseded by less toxic paints based on titanium dioxide. In the nineteenth century lead(II) nitrate began to be produced commercially in Europe and the United States. Known since the Middle Ages by the name plumbum dulce, the production of lead(II) nitrate from either metallic lead or lead oxide in nitric acid was small-scale, for direct use in making other lead compounds. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water. Lead(II) nitrate is an inorganic compound with the chemical formula Pb( NO 3) 2.
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